Show transcribed image text (15 pts) 1. Write structural formulas for each of the following: (a) 3-heptanol (b) trans-4-tert-butylcyclohexanol (c) vinyl chloride 2. Write the structure of the major organic product expected from each of the following reactions. (108 pts) (a) 1-butanol+PBrs (b) 2-methylpropane + Br2+ light (c) 1-bromo-3,3-dimethylbutane + potassium tert-butoxide +tert-butyl alcohol+heat (d) tert-butyl chloride +sodium ethoxide (CH3CH2ONa) + ethanol (e) 1-pentene +HCI (f) 2-methyl-2-butene + HBr in the presence of 1% peroxide (ROR) (g) 3,3-dimethyl-2-butanol + H2S04 +heat (h) cyclohexene + Br2 (i) 1,2-dimethylcyclohexene +H2 +Pt catalyst 3. Show a sequence of reactions suitable for converting: (30 pts) (a) cyclohexane to cyclohexene (b) 1-pentene to 1-pentanol (c) (CH3)2C C(CH3)2 to (CH3)2C-o 4. Which alkene will react fastest with HCl: (20 pts) ethene, propene, 2-methylpropene, or 2.3-dimethyl-2-butene. Justify your answer.
(15 pts) 1. Write structural formulas for each of the following: (a) 3-heptanol (b) trans-4-tert-butylcyclohexanol (c) vinyl chloride 2. Write the structure of the major organic product expected from each of the following reactions. (108 pts) (a) 1-butanol+PBrs (b) 2-methylpropane + Br2+ light (c) 1-bromo-3,3-dimethylbutane + potassium tert-butoxide +tert-butyl alcohol+heat (d) tert-butyl chloride +sodium ethoxide (CH3CH2ONa) + ethanol (e) 1-pentene +HCI (f) 2-methyl-2-butene + HBr in the presence of 1% peroxide (ROR) (g) 3,3-dimethyl-2-butanol + H2S04 +heat (h) cyclohexene + Br2 (i) 1,2-dimethylcyclohexene +H2 +Pt catalyst 3. Show a sequence of reactions suitable for converting: (30 pts) (a) cyclohexane to cyclohexene (b) 1-pentene to 1-pentanol (c) (CH3)2C C(CH3)2 to (CH3)2C-o 4. Which alkene will react fastest with HCl: (20 pts) ethene, propene, 2-methylpropene, or 2.3-dimethyl-2-butene. Justify your answer.





