The term adiabatic lapse rate used by meteorologists is the
decrease in temperature with height that results from the adiabatic
expansion of an air mass as it is pushed up a mountain by the wind.
Similarly, the wind coming down the mountain slope warms up. This
adiabatic expansion is represented by P0, V0,
T0 P, V, T
where ΔS = 0 and P0, V0, T0
represents the sea level conditions. The calculation of the entropy
change can be carried out in two steps: the first at constant
pressure P0, V0, T0
P0, V*, T, the second at constant temperature
P0, V*, T0 P, V,
T.
a. Calculate ΔS1 and ΔS2, the change in entropy for the two
steps above.
b. Since ΔS = ΔS1 + ΔS2, what is the expression for ΔT/Δh. To
derive this use the expression for the change in pressure with
height in the atmosphere from Problem Set 2 (Pi =
Pi,0 exp(-Migh / RT).
c. If the temperature at the foot of a 14,000-foot mountain is
25 °C, what temperature would you expect at the summit from this
adiabatic lapse rate? For this calculation the molar mass of air
can be taken to be M = 29 g mol-1 and its heat capacity
can be taken as 29.1 J K-1mol-1.





